Two 3D coordination polymers constructed from flexible desymmetric carboxylate and neutral nitrogen ligands

Ping Yun-Jie Yan Ru-Yong Zhao Gao-Chao Qin Ling Zheng Hegen · 2015

阅读量：88

配位聚合物

碳氨基酸配体

二次谐波的产生

期刊名称：

Inorganic Chemistry Communications 2015 年 61 卷

发表日期：

2015.11.01

摘要：

Two coordination polymers based on a flexible desymmetric ligand precursor H2L have been synthesized, that is, [Ni(L)(dpe)3/2] H2O (1), [Ni2(H2O)(L)2(bpp)2] H2O (2), [H2L = 4,4???-(phenylazanediyl)dibenzoic acid, dpe = 1,2-di(pyridin-4-yl)ethane, bpp = 1,3-di(pyridin-4-yl)propane]. These complexes were characterized by elemental analysis, IR spectroscopy, X-ray single-crystal and power diffraction. In addition, the second nonlinear optical properties of 2 were measured.