Well-Dispersed ZIF-Derived Co,N-Co-doped Carbon Nanoframes through Mesoporous-Silica-Protected Calcination as Efficient Oxygen Reduction Electrocatalysts

Shang Lu Yu Huijun Huang Xing Bian Tong Shi Run Zhao Yufei Waterhouse Geoffrey I. N. Wu Li-Zhu Tung Chen-Ho Zhang Tierui · 2016

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公司n-co-doped碳

期刊名称：

Advanced Materials 2016 年 28 卷 8 期

发表日期：

2016.02.24

摘要：

A well-dispersed Co,N co-doped carbon nanoframework (Co,N-CNF) with hierarchically porous structure is successfully synthesized from zeolitic imidazolate framework (ZIF) precursors via a mesoporous-silica-protected calcination strategy. By preventing the irreversible fusion and aggregation during the high-temperature pyrolysis step with this protection strategy, the Co,N-CNF exhibits comparable oxygen reduction reaction (ORR) catalytic activity to that of commercial Pt catalysts with the same loading.