Palladium catalyzed mono and difunctionalization of hexafluorobut-2-yne
Zhao Bo
Li Yang
Tu Dong-Huai
Zhang Wei
Liu Zhao-Tie
Lu Jian
· 2016
期刊名称:
Tetrahedron Letters
2016 年
57 卷
39 期
摘要:
The Pd(0) catalyzed one-pot mono and difunctionalization of hexafluorobut-2-yne is investigated. Styrenes and stilbenes can be obtained in high stereoselectivity by carbopalladation of phenylboronic acids and iodide benzenes. The reactions afford a facile access to a broad scope with good functional compatibility.