Particle and Particle Systems Characterization   2016 年 33 卷 4 期

2016.04.01

Presently, graphene incorporation is one of the most effective strategies to develop superior electrode materials for sodium-ion batteries (SIBs). Herein, it is excitingly found that an incorporated graphene nanosheet in the preparation processes can not only completely protect all the Sb nanoparticles in an Sb/C composite from being inactivated, but also suppresses their growth to undesirable micrometer size. While there are still many exposed Sb particulates on the surface of pristine Sb/C microplates, the graphene-incorporated Sb/C/G nanocomposite consists of uniform Sb nanoparticles of 20-50 nm, all of which have been protected by and wrapped in the mixed carbon network. When used as anode materials for SIBs, the Sb/C/G nanocomposite exhibits the best Na-storage properties in terms of the highest reversible capacity (650 mA h g