Journal of Analytical and Applied Pyrolysis   2015 年 112 卷

2015.03.01

By avoiding the massive calculations of complicated reaction networks, the continuous lumping method has been welcomed as a means of describing hydrocarbon pyrolysis processes. In our work, with the introduction of a new distribution function representing different structure effects on kinetic parameters, a mechanism-oriented continuous lumping model is proposed to acquire the olefin profile of naphtha pyrolysis with experimentation independent of different feeding compositions. Meanwhile, micro-reactor pyrolysis experiments are conducted to analyze the structure mechanism and to obtain the pyrolysis parameters. The analytical results indicate that long-chain molecules with higher degrees of branching react faster, and long-chain alkanes with fewer side chains are more inclined to form ethylene product. The prediction results of the simulation method are consistent with the experimental results. The prediction performance is comparatively accurate and independent of feeding.